通过对市场的调查回访我们发现，很多客户对顺酐的制备方法还不是了解的很明白，今天小编就将查阅的相关资料与大家分享一下，希望引起大家的重视，让大家对顺酐厂家有一个深层次的了解。这样大家在购买使用山东顺酐时也能做到心中有数，不怕上当受骗，希望对大家有所启发与帮助。
Through the market survey, we found that many customers do not understand the preparation method of maleic anhydride very well. Today, I will share the relevant information with you, hoping to arouse your attention and let you have a deep understanding of maleic anhydride manufacturers. In this way, when you buy and use Shandong maleic anhydride, you can also have a clear idea, and you are not afraid of being cheated. I hope it will inspire and help you.
1. 苯氧化制顺酐
1. Oxidation of benzene to maleic anhydride
将苯与空气混合(苯为1%-1.4% )经换热器预热后，进人列管式催化反应器。在压力为0.1-0.2MPa、温度为350-400℃的反应条件下进行氧化反应，所得产物经两台换热器、一台冷却器后，冷却到接近露点(55―65℃)。冷却后的反应物进入分离器，分离器底部得粗顺酐，进入粗顺酐罐。
The mixture of benzene and air (benzene is 1% - 1.4%) is preheated by heat exchanger and then put into tubular catalytic reactor. The oxidation reaction was carried out under the reaction conditions of 0.1-0.2mpa pressure and 350-400 ℃ temperature. The product was cooled to near dew point (55-65 ℃) by two heat exchangers and one cooler. The cooled reactant enters the separator, and crude maleic anhydride is obtained at the bottom of the separator and enters the crude maleic anhydride tank.
分离器顶部流出物进人洗涤塔，用水洗涤，塔顶为多余空气和未反应的苯，苯可用吸附回收。洗涤塔塔底水溶液进人脱水器，分离出水，所得粗顺酐进人粗顺酐罐。粗顺酐进一步进人蒸馏塔进行蒸馏精制，得顺酐。所得顺酐可进行异构化得富马酸和苹果酸。
The effluent from the top of the separator enters the scrubber and is washed with water. The top of the scrubber contains excess air and unreacted benzene, which can be recovered by adsorption. The water solution at the bottom of the washing tower enters the dehydrator to separate the water, and the obtained crude maleic anhydride enters the crude maleic anhydride tank. The crude maleic anhydride is further put into a distillation tower for distillation and refining to obtain maleic anhydride. The obtained maleic anhydride can be isomerized to give fumaric acid and malic acid.
2.C4馏分部分氧化制顺酐
2. Partial oxidation of C4 fraction to maleic anhydride
工业上用不经分离的C4馏分或分离异丁烯和丁二烯后的C4馏分为原料顺酐。C4馏分与空气混合后进人流化床氧化反应器，在300―500℃温度下，与反应器中的催化剂接触顺酐。氧化反应器顶部流出的反应生成物进人吸收塔，用水作为吸收剂，塔顶气体经废水。
Maleic anhydride is produced from C4 fraction without separation or C4 fraction after separation of isobutene and butadiene. The mixture of C4 fraction and air was fed into a fluidized bed oxidation reactor to produce maleic anhydride at 300-500 ℃. The reaction product from the top of the oxidation reactor flows into the absorption tower, water is used as the absorbent, and the top gas passes through the waste water.
